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By Shinji Murai

The important suggestion of this quantity is to supply a Capita Selecta of unconventional and thought-provoking issues in organometallic chemistry, awarded through specialists in every one box. As meant, this process leads both to experiences protecting a particular unusual type of organometallic compounds or to overviews which relate unusual actual homes with numerous sessions of organometallic compounds. content material: constitution and electrochemistry of transition steel carbonyl clusters with interstitial or semi-interstitial atoms: distinction among nitrides or phosphides and carbides / Piero Zanello -- strange nuclear magnetic defensive and coupling constants on the topic of strange bonding occasions / Bernd Wrackmeyer -- Deuterium spin lattice rest and deuterium quadrupole coupling constants. a unique procedure for characterization of transition steel hydrides and dihydrogen complexes in answer / Vladimir I. Bakhmutov -- NMR experiences of ligand nuclei in organometallic compounds -- new info from solid-state NMR thoughts / man M. Bernard, Roderick E. Wasylishen -- steel atom movement in a few iron organometallics / Rolfe H. Herber -- Magnetic verbal exchange in binuclear organometallic complexes mediated by way of carbon-rich bridges / Frďřic Paul, Claude Lapinte -- Molecular cluster complexes with facial arene ligands / Herbert Wadepohl -- Cobaltafulvenes and cobaltapentalenes: hugely polar metallacyclic II-systems with strange houses / Herbert Wadepohl -- Novel hugely nucleophilic ylidic ligands for the education of strangely good steel complexes / Norbert Kuhn, Martin Göhner, Gernot Frenking, Yu Chen -- Supramolecular interactions in buildings of natural antimony and Bismuth compounds / Gabor Balz̀s, Hans Joachim Breunig. summary: The crucial notion of this quantity is to supply a Capita Selecta of unconventional and thought-provoking themes in organometallic chemistry, provided through specialists in every one box. As meant, this method leads both to studies protecting a selected unusual classification of organometallic compounds or to overviews which relate unusual actual homes with numerous periods of organometallic compounds

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1 Addition of C–H Bonds to Carbon-Carbon Double Bonds Catalytic additions of carbon-hydrogen bonds to olefins would constitute one of the most efficient, economical methods for constructing a carbon-carbon framework. In 1978, Yamazaki et al. reported pioneering studies of the catalytic functionalization of C–H bonds [7]. Reaction of benzene, used as a solvent, with diphenylketene in the presence of Rh4(CO)12 as the catalyst gave the corresponding diphenylmethyl phenyl ketone in good yield with moderate selectivity (Eq.

76 Topics in Organometallic Chemistry, Vol. 3 Volume Editor: S. Murai © Springer-Verlag Berlin Heidelberg 1999 48 Fumitoshi Kakiuchi, Shinji Murai 1 Introduction One of the most valuable synthetic methods in organic synthesis is the direct use of otherwise unreactive C–H bonds with the aid of transition metal complexes. Since Kleiman and Dubeck reported in 1963 the possibility of cleavage of C–H bonds in azobenzene by Cp2Ni complex [1], many research groups have reported the cleavage of C–H bonds by using stoichiometric amounts of transition metal complexes [2].

75 References . . . . . . . . . . . . . . . . . . . 76 Topics in Organometallic Chemistry, Vol. 3 Volume Editor: S. Murai © Springer-Verlag Berlin Heidelberg 1999 48 Fumitoshi Kakiuchi, Shinji Murai 1 Introduction One of the most valuable synthetic methods in organic synthesis is the direct use of otherwise unreactive C–H bonds with the aid of transition metal complexes. Since Kleiman and Dubeck reported in 1963 the possibility of cleavage of C–H bonds in azobenzene by Cp2Ni complex [1], many research groups have reported the cleavage of C–H bonds by using stoichiometric amounts of transition metal complexes [2].

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